化学工程与技术

刘 晰

阅读次数:     日期:2024-03-11


姓名:刘 晰

民族:汉

学历:博士研究生

职称:教授

邮箱:liuxi@sjtu.edu.cn

办公室电话:

(1)异相催化 (2)绿色化工 (3)先进表征方法学 (4)原位电子显微镜


教育背景与工作经历

1992-09 至 1997-07, 中国科技大学, 材料化学, 学士。

1999-09 至 2002-07, 中国科学院成都有机化学研究所, 物理化学, 硕士。

2004-06 至 2008-09, Fritz-Haber Institute, 物理化学, 博士。

2009-01 至 2014-12, 卡迪夫大学,卡迪夫催化中心,副研究员。

2015-01 至 2015-10, 丹麦技术大学, 纳米电镜中心, 研究员。

2015-10 至 2019-11, 中科合成油技术有限公司, 表面实验室, 高级工程师。

2019-11 至 2024-02, 上海交通大学, 学院, 研究员。

2024-02 至今, 我校, 学院(省部共建煤炭高效利用与绿色化工国家重点实验室), 教授。

科研成果

刘晰教授主要从事异相催化、绿色化工和先进表征方法学及表面科学研究。主持了4项国家基金委面上项目,参与2项国家科技部国家重大专项课题,主持了多项与国外化工公司委托项目。在包括Science,Nat. Energy, Nat. Synth.,Nat. Catal., Nat. Comm., JACS, Angew. Chem., ACS Catal., Nano Lett.等国际知名科学期刊共发表SCI论文超过180余篇。入选2022年教育部“长江学者”特聘教授。

部分文章

1.Xiaohu Ge, Jun Yin, Zhouhong Ren, Kelin Yan, Yundao Jing, Yueqiang Cao*, Nina Fei, Xi Liu*, Xiaonan Wang*, Xinggui Zhou, Liwei Chen, Weikang Yuan, Xuezhi Duan*, “Atomic Design of Alkyne Semihydrogenation Catalysts via Active Learning” J. Am. Chem. Soc, 146 (7), 4993-5004 (2024)。

2.Junhong Liu, Liwei Chen, Xi Liu, “Deep Insight into Characterizing the Metal–Support Interface in Heterogeneous Catalysis” ACS Catal, 14(3): 1987-2002 (2024)。

3.Xuetao Qin, Ming Xu, Jianxin Guan, Li Feng, Yao Xu, Lirong Zheng, Meng Wang, Jian-Wen Zhao, Jia-Lan Chen, Jie Zhang, Jinglin Xie, Zhihao Yu, Ruiqi Zhang, Xinmao Li, Xi Liu, Jin-Xun Liu, Junrong Zheng, Ding Ma, “Direct conversion of CO and H2O to hydrocarbons at atmospheric pressure using a TiO2− x/Ni photothermal catalyst.” Nat Energy, 1-9 (2024)。

4.Rui-Ping Zhang, Bowen He, Xi Liu, and An-Hui Lu, “Hydrogen Spillover-Driven Dynamic Evolution and Migration of Iron Oxide for Structure Regulation of Versatile Magnetic Nanocatalysts” J. Am. Chem. Soc, 145(47): 25834-25841 (2023)。

5.Bowen He, Xin Tao, Lina Li, Xi Liu, and Liwei Chen, “Environmental TEM Study of the Dispersion of Au/α-MoC: From Nanoparticles to Two-Dimensional Clusters” Nano Lett, 23(22): 10367-10373 (2023)。

6.Yuanfeng Li, Tian Qin, Yuechang Wei, Jing Xiong, Peng Zhang, Kezhen Lai, Hongjie Chi, Xi Liu, Liwei Chen, Xiaolin Yu, Zhen Zhao, Lina Li, Jian Liu, “A single site ruthenium catalyst for robust soot oxidation without platinum or palladium” Nat Commun, 14(1): 7149 (2023)。

7.Tianfu Wang, Jianghao Wang, Chenbao Lu, Kaiyue Jiang, Sen Yang, Zhouhong Ren, Jichao Zhang, Xi Liu, Liwei Chen, Xiaodong Zhuang, Jie Fu, “Single‐Atom Anchored Curved Carbon Surface for Efficient CO2 Electro‐Reduction with Nearly 100% CO Selectivity and Industrially‐Relevant Current Density” Advanced Materials, 35(35): 2205553 (2023)。

8.Jian Sheng, Wen-Cui Li, Bowen He, Xin-Qian Gao, Wen-Duo Lu, Bin Qiu, Rui-Ping Zhang, Lei He, Xi Liu, and An-Hui Lu, “Surface Borate-Derived Highly Dispersed and Stable Metal Nanoparticles on Nitrogen-Vacancy Boron Nitride Support Promoting CO Methanation” ACS Catal, 13: 9201-9212 (2023)。

9.Rui-Ping Zhang, Bowen He, Ren-Peng Yang, Yu-Xiang Zhang, Wen-Cui Li, Li-Han Zhu, Si-Jia Wang, Dong-Qi Wang, Xi Liu, Liwei Chen, Cheng-Wei Wu, An-Hui Lu, “Nanoengineered design of inside‐heating hot nanoreactor surrounded by cool environment for selective hydrogenations” Advanced Materials, 2302793 (2023)。

10.Ming-Yuan Shen, Jing-Song Wang, Zhouhong Ren, Tao Wu, Xi Liu, Liwei Chen, Wen-Cui Li, An-Hui Lu, “Quasi‐Zero Volume Strain Cathode Materials for Sodium Ion Battery through Synergetic Substitution Effect of Li and Mg” Advanced Functional Materials, 2303812 (2023)。

11.Bowen He, Xi Liu, and Liwei Chen,“Particle Attachment Growth of Au@ Ag Core–Shell Nanocuboids” Nano Lett, 23(9): 3963-3970 (2023)。

12.Alex Stenner, Richard J. Lewis, Joseph Brehm, Tian Qin, Ángeles López-Martín, David J. Morgan, Thomas E. Davies, Liwei Chen, Xi Liu, Graham J. Hutchings, “Chemo‐Enzymatic One‐Pot Oxidation of Cyclohexane via in‐situ H2O2 Production over Supported AuPdPt Catalysts” ChemCatChem, 15(10): e202300162 (2023)。

13.Yuanfeng Li, Tian Qin, Yaxiao Ma, Jing Xiong, Peng Zhang, Kezhen Lai, Xi Liu, Zhen Zhao, Jian Liu, Liwei Chen, Yuechang Wei, “Revealing active edge sites induced by oriented lattice bending of Co-CeO2 nanosheets for boosting auto-exhaust soot oxidation” Journal of Catalysis, 421: 351-364 (2023)。

14.Yinghui Pu, Bowen He, Yiming Niu, Xi Liu,Bingsen Zhang, “Chemical Electron Microscopy (CEM) for Heterogeneous Catalysis at Nano: Recent Progress and Challenges” Research, 6: 0043 (2023)。

15.Peng Zhang, Min Yang, Dawei Han, Xi Liu, Xiaolin Yu, Jing Xiong, Yuanfeng Li, Zhen Zhao, Jian Liu, Yuechang Wei, “Activating well-defined α-Fe2O3 nanocatalysts by near-surface Mn atom functionality for auto-exhaust soot purification” Applied Catalysis B: Environmental, 321: 122077 (2023)。

16.Gui Liu, Pengfei Liu, Deming Meng, Taotao Zhao, Xiaofeng Qian, Qiang He, Xuefeng Guo, Jizhen Qi, Luming Peng, Nianhua Xue, Yan Zhu, Jingyuan Ma, Qiang Wang, Xi Liu, Liwei Chen, Weiping Ding, “COx hydrogenation to methanol and other hydrocarbons under mild conditions with Mo3S4@ ZSM-5” Nat. Commun, 14(1): 513 (2023)。

17.Richard J. Lewis, Kenji Ueura, Xi Liu, Yukimasa Fukuta, Tian Qin, Thomas E. Davies, David J. Morgan, Alex Stenner, James Singleton, Jennifer K. Edwards, Simon J. Freakley, Christopher J. Kiely, Liwei Chen, Yasushi Yamamoto, and Graham J. Hutchings, “Selective Ammoximation of Ketones via In Situ H2O2 Synthesis” ACS Catal, 13(3): 1934-1945 (2023)。

18.Tao Tong, Mark Douthwaite, Lu Chen, Rebecca Engel, Matthew B. Conway, Wanjun Guo, Xin-Ping Wu, Xue-Qing Gong, Yanqin Wang, David J. Morgan, Thomas Davies, Christopher J. Kiely, Liwei Chen, Xi Liu, and Graham J. Hutchings, “Uncovering Structure–Activity Relationships in Pt/CeO2 Catalysts for Hydrogen-Borrowing Amination” ACS Catal, 13(2): 1207-1220 (2023)。

19.Dávid Kovačič, Richard J. Lewis, Caitlin M. Crombie, David J. Morgan, Thomas E. Davies, Ángeles López-Martín, Tian Qin, Christopher S. Allen, Jennifer. K. Edwards , Liwei Chen, Martin Skov Skjøth-Rasmussen, Xi Liu, Graham J. Hutchings, “A comparative study of palladium-gold and palladium-tin catalysts in the direct synthesis of H2O2” Green Chemistry, 25(24): 10436-10446 (2023)。

20.Ming Xu, Xuetao Qin, Yao Xu, Xiaochen Zhang, Lirong Zheng, Jin-Xun Liu, Meng Wang, Xi Liu, Ding Ma, “Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2−x/Ni catalysts” Nat. Commun, 13(1): 6720 (2022)。

21.Weiye Qu, Haiyang Yuan, Zhouhong Ren, Jizhen Qi, Dongrun Xu, Junxiao Chen, Liwei Chen, Huagui Yang, Zhen Ma, Xi Liu, Haifeng Wang, Xingfu Tang, “An Atom‐Pair Design Strategy for Optimizing the Synergistic Electron Effects of Catalytic Sites in NO Selective Reduction” Angewandte Chemie, 134(52): e202212703 (2022)。

22.Lu Liu, Huan Li, Hang Zhou, Shengqi Chu, Lujie Liu, Zhaochi Feng, Xuedi Qin, Jizhen Qi, Jue Hou, Qinming Wu,1 Hangjie Li,5 Xi Liu*, Liwei Chen, Jianping Xiao*, Liang Wang*, and Feng-Shou Xiao, “Rivet of cobalt in siliceous zeolite for catalytic ethane dehydrogenation” Chem, 9(3): 637-649 (2022)。

23.Xiaohu Ge, Mingying Dou, Yueqiang Cao, Xi Liu, Qiang Yuwen,  Jing Zhang, Gang Qian, Xueqing Gong, Xinggui Zhou, Liwei Chen, Weikang Yuan, Xuezhi Duan, “Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene” Nat. Commun, 13(1): 5534 (2022)。

24.Joseph Brehm, Richard J. Lewis, Thomas Richards, Tian Qin, David J. Morgan, Thomas E. Davies, Liwei Chen, Xi Liu, and Graham J. Hutchings, “Enhancing the chemo-enzymatic one-pot oxidation of cyclohexane via in situ H2O2 production over supported pd-based catalysts” ACS Catal, 12(19): 11776-11789 (2022)。

25.Qi Hao, Hai-xia Zhong, Jia-zhi Wang, Kai-hua Liu, Jun-min Yan, Zhou-hong Ren, Na Zhou, Xiao Zhao, Hao Zhang, Dong-xue Liu, Xi Liu, Li-wei Chen, Jun Luo, Xin-bo Zhang, “Nickel dual-atom sites for electrochemical carbon dioxide reduction” Nature Synthesis, 1(9): 719-728 (2022)。

26.Wenwen Lin, Hao Chen, Gaobo Lin, Siyu Yao, Zihao Zhang, Jizhen Qi, Meizan Jing, Weiyu Song, Jing Li, Xi Liu, Jie Fu, Sheng Dai, “Creating frustrated Lewis pairs in defective boron carbon nitride for electrocatalytic nitrogen reduction to ammonia” Angewandte Chemie International Edition, 61(36): e202207807 (2022)。

27.Yang Yang, Xiaojuan Zhu, Lili Wang, Junyu Lang, Guohua Yao, Tian Qin, Zhouhong Ren, Liwei Chen, Xi Liu, Wei Li, Ying Wan, “Breaking scaling relationships in alkynol semi-hydrogenation by manipulating interstitial atoms in Pd with d-electron gain” Nat. Commun, 13(1): 2754 (2022)。

28.Richard J. Lewis, Kenji Ueura, Xi Liu, Yukimasa Fukuta, Thomas E. Davies, David J. Morgan,  LiWei Chen, JiZhen Qi, James Singleton, Jennifer.K.Edwards, Simon J. Freakley, Christopher J. Kiely, Yasushi Yamamoto, Graham J. Hutchings, “Highly efficient catalytic production of oximes from ketones using in situ–generated H2O2” Science, 376(6593): 615-620 (2022)。

29.Yuxi Fang, Xi Liu, Zhipan Liu*, Lu Han*, Jing Ai, Gui Zhao, Osamu Terasaki, Cunhao Cui, Jiuzhong Yang, Chengyuan Liu, Zhongyue Zhou*, Liwei Chen, Shunai Che*, “Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces” Chem, 9(2): 460-471 (2022)。

30.Jiayi Fu, Shizhong Liu, Weiqing Zheng, Renjing Huang, Cong Wang, Ajibola Lawal, Konstantinos Alexopoulos, Sibao Liu, Yunzhu Wang, Kewei Yu, J. Anibal Boscoboinik, Yuefeng Liu, Xi Liu, Anatoly I. Frenkel, Omar A. Abdelrahman, Raymond J. Gorte, Stavros Caratzoulas, Dionisios G. Vlachos, “Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst” Nature Catalysis, 5(2): 144-153 (2022)。

31.Jincan Kang, Qi-Yuan Fan, Wei Zhou, Qinghong Zhang, Shun He, Liangxu Yue, Yu Tang, Luan Nguyen, Xiang Yu, Yong You, Haohao Chang, Xi Liu*, Liwei Chen, Yuefeng Liu, Franklin Tao*, Jun Cheng*, and Ye Wang*, “Iridium boosts the selectivity and stability of cobalt catalysts for syngas to liquid fuels” Chem, 8(4): 1050-1066 (2022)。

32.Lili Lin, Jinjia Liu, Xi Liu, Zirui Gao, Ning Rui, Siyu Yao, Feng Zhang, Maolin Wang, Chang Liu, Lili Han, Feng Yang, Sen Zhang, Xiao-dong Wen, Sanjaya D. Senanayake, Yichao Wu, Xiaonian Li, José A. Rodriguez, Ding Ma, “Reversing sintering effect of Ni particles on γ-Mo2N via strong metal support interaction” Nat. Commun. 12(1): 6978 (2021)。

33.Xiu Lin, Shi-Nan Zhang, Dong Xu, Jun-Jun Zhang, Yun-Xiao Lin, Guang-Yao Zhai, Hui Su, Zhong-Hua Xue, Xi Liu, Markus Antonietti, Jie-Sheng Chen, Xin-Hao Li. “Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution” Nat. Commun. 12(1): 3882 (2021)。

34.Qian Jiang, Wen Luo, Yuang Piao, Hiroaki Matsumoto, Xi Liu, Andreas Züttel, Ksenia Parkhomenko, Cuong Pham-Huu, and Yuefeng Liu, “Surface Oxygenate Species on TiC Reinforce Cobalt-Catalyzed Fischer–Tropsch Synthesis” ACS Catal, 11(13): 8087-8096 (2021)。

35.Yaxin Chen, Daiming Tang, Zhiwei Huang, Xi Liu, Jun Chen, Takashi Sekiguchi, Weiye Qu, Junxiao Chen, Dongrun Xu, Yoshio Bando, Xiaolei Hu, Xiaoping Wang, Dmitri Golberg, Xingfu Tang, “Stable single atomic silver wires assembling into a circuitry-connectable nanoarray” Nat. Commun.  12(1): 1191 (2021)。

36.Caitlin M. Crombie, Richard J. Lewis, Rebekah L. Taylor, David J. Morgan, Thomas E. Davies, Andrea Folli, Damien M. Murphy, Jennifer K. Edwards, Jizhen Qi, Haoyu Jiang, Christopher J. Kiely, Xi Liu, Martin Skov Skjøth-Rasmussen, and Graham J. Hutchings, “Enhanced selective oxidation of benzyl alcohol via in situ H2O2 production over supported Pd-based catalysts” ACS Catal. 11(5): 2701-2714 (2021)。

37.Yanhui Yi, Xin Wang, Amin Jafarzadeh, Li Wang, Pei Liu, Bowen He, Jinhui Yan, Rui Zhang, Hantian Zhang, Xi Liu, Hongchen Guo, Erik C. Neyts, and Annemie Bogaerts, “Plasma-catalytic ammonia reforming of methane over Cu-based catalysts for the production of HCN and H2 at reduced temperature” ACS Catal., 11(3): 1765-1773 (2021)。

38.Chenji Hu, Yanbin Shen, Ming Shen, Xi Liu, Hongwei Chen, Chenghao Liu, Tuo Kang, Feng Jin, Li Li, Jing Li, Yiqiu Li, Ning Zhao, Xiangxin Guo, Wei Lu, Bingwen Hu, and Liwei Chen, “Superionic conductors via bulk interfacial conduction” J. Am. Chem. Soc., 142(42): 18035-18041 (2020)。

39.Chuqiao Song, Xi Liu, Ming Xu, Daniel Masi, Yigui Wang, Yuchen Deng, Mengtao Zhang, Xuetao Qin, Kai Feng, Jie Yan, Jing Leng, Zhaohua Wang, Yao Xu, Binhang Yan, Shengye Jin, Dongsheng Xu, Zhen Yin, Dequan Xiao, and Ding Ma, “Photothermal conversion of CO2 with tunable selectivity using Fe-based catalysts: from oxide to carbide” ACS Catal., 10(18): 10364-10374 (2020)。

40.Yao Xu, Peng Zhai, Yuchen Deng, Jinglin Xie, Xi Liu, Shuai Wang, Prof. Ding Ma, “Highly selective olefin production from CO2 hydrogenation on iron catalysts: a subtle synergy between manganese and sodium additives” Angewandte Chemie, 132(48): 21920-21928 (2020)。

41.Yinwen Li, Wa Gao, Mi Peng, Junbo Zhang, Jialve Sun, Yao Xu, Song Hong, Xi Liu, Xingwu Liu, Min Wei, Bingsen Zhang, Ding Ma “Interfacial Fe5C2-Cu catalysts toward low-pressure syngas conversion to long-chain alcohols” Nat. Commun.  11(1): 61 (2020)。

42.Jian Gao, Yun Wang, Haihua Wu, Xi Liu, Leilei Wang, Qiaolin Yu, Aowen Li, Hong Wang, Chuqiao Song, Zirui Gao, Mi Peng, Mengtao Zhang, Na Ma, Jiaou Wang, Wu Zhou, Guoxiong Wang, Zhen Yin, Ding Ma, “Construction of a sp3/sp2 carbon interface in 3D N‐doped nanocarbons for the oxygen reduction reaction” Angewandte Chemie International Edition, 58(42): 15089-15097 (2019)。

43.Dui Ma, Bo Hu, Wenda Wu, Xi Liu, Jiantao Zai, Chen Shu, Tsegaye Tadesse Tsega, Liwei Chen, Xuefeng Qian, T. Leo Liu, “Highly active nanostructured CoS2/CoS heterojunction electrocatalysts for aqueous polysulfide/iodide redox flow batteries” Nat. Commun.,10(1): 3367 (2019)。

44.Yao Xu, Jing Li, Wenjing Li, Weizhen Li, Xiaochen Zhang, Yue Zhao, Jinglin Xie, Xiaoping Wang, Xi Liu, Yongwang Li, Dequan Xiao, Zhen Yin, Yong Cao, Ding Ma, “Direct conversion of CO and H2O into liquid fuels under mild conditions” Nat. Commun. 10(1): 1389 (2019)。

45.Yiming Niu, Xi Liu, Yongzhao Wang, Song Zhou, Zhengang Lv, Liyun Zhang, Wen Shi, Yongwang Li, Wei Zhang, Dang Sheng Su, Bingsen Zhang, “Visualizing formation of intermetallic PdZn in a palladium/zinc oxide catalyst: Interfacial fertilization by PdHx”  Angewandte Chemie International Edition, 58(13): 4232-4237 (2019)。

46James H. Carter, Xi Liu, Qian He, Sultan Althahban, Ewa Nowicka, Simon J. Freakley, Liwei Niu, David J. Morgan, Yongwang Li, J. W. (Hans) Niemantsverdriet, Stanislaw Golunski, Christopher J. Kiely, Graham J. Hutchings, “Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction” Angewandte Chemie International Edition, 56(50): 16037-16041 (2017)。

47.Xi Liu, Chenghua Zhang, Yongwang Li, J. W. Niemantsverdriet, Jakob B. Wagner, and Thomas W. Hansen, “Environmental transmission electron microscopy (ETEM) studies of single iron nanoparticle carburization in synthesis gas” ACS Catal., 7(7): 4867-4875 (2017)。

48.Liu, X., Frank, B., Zhang, W., Cotter, T. P., Schlögl, R., & Su, D. S. “Carbon-catalyzed oxidative dehydrogenation of n-butane: selective site formation during sp3-to-sp2 lattice rearrangement” Angewandte Chemie International Edition, 50(14): 3318-3322 (2011)。

49.Yong-Sheng Hu, Xi Liu, Jens-O. Müller, Robert Schlögl, Dang Sheng Su, “Synthesis and electrode performance of nanostructured V2O5 by using a carbon tube‐in‐tube as a nanoreactor and an efficient mixed‐conducting network” Angewandte Chemie International Edition, 48(1): 210-214 (2009)。

50.Jian Zhang, Xi Liu, Raoul Blume, AiHua Zhang, Robert Schlogl, Dang Sheng Su, “Surface-modified carbon nanotubes catalyze oxidative dehydrogenation of n-butane” Science, 322(5898): 73-77 (2008)。


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